Analysis of Beta-Carotene, Tocopherol and Fatty Acid in Red Palm Oil for Development as Soap Products

Authors

  • Nipaporn Meepun Faculty of Science and Technology, Suratthani Rajabhat University
  • Pongsak Noparat Faculty of Science and Technology, Suratthani Rajabhat University

Keywords:

red palm oil , oil palm , beta-carotene , tocopherol , soap

Abstract

Background and Objectives : Palm oil is a type of oil that can be used as a source of fatty acids, which are cleaning agents produced from the reaction of fats with strong alkalis. Red palm oil is a crude palm oil obtained specifically from pressing the fruit's flesh and has not undergone bleaching. It has a balanced composition of saturated and unsaturated fatty acids and is rich in important nutrients. Therefore, the aim of this research is to analyze the amount levels of beta-carotene, tocopherols, and fatty acids in red palm oil obtained from pressing the pulp of fallen oil palm fruit, and to develop bar soap products from it. The results of this study can provide a pathway for generating income and increasing the value of palm oil products during periods when palm oil prices fluctuate according to market dynamics.

Methodology : Red palm oil obtained from extraction was analyzed for beta-carotene and tocopherols using high-performance liquid chromatography techniques. The fatty acid content was analyzed using gas chromatography. The oil was then used to develop bar soap products. The resulting soap was tested for user satisfaction and evaluated for its physical characteristics and chemical properties.

Main Results : The analysis of red palm oil found that the amount of beta-carotene and tocopherol was 60.89 and 21.67 mg/100g, respectively. The fatty acid content included lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, palmitoleic acid, linoleic acid, and linolenic acid, found at percentages of 0.25, 1.15, 39.11, 3.80, 0.36, 0.17, 9.96, and 0.35 by mass, respectively. User satisfaction testing regarding sensory characteristics, including foam quantity, skin cleansing ability, skin moisture, fragrance, color, and soap hardness, was conducted with 30 users. The results indicated that formulation C had the highest overall satisfaction score of 6.92. Physical testing showed a pH value of 9.76±0.02, an immediate foam volume of 27.00±2.00 mL after shaking, and corrosion percentage of 15.25±1.53. For the chemical properties, the insoluble matter in ethanol was found to be 1.92±0.35%, total fat matter content was 64.57±1.29%, and no free caustic alkali content was detected.

Conclusions : Red palm oil is rich in beta-carotene, tocopherols, and both saturated and unsaturated fatty acids. When developed into soap products and assessed for their physical and chemical properties, they were found to meet the criteria of community product standards and industrial product standards. This ensures safety for use and serves as a pathway for generating income, adding value to palm oil.

References

Abbasalipourkabir, R., Salehzadeh, A., & Abdullah, R. (2012). Characterization and stability of nanostructured lipid carriers as drug delivery system. Pakistan Journal of Biological Sciences, 15(3), 141-146.

Ayeleso, A.O., Oguntibeju, O.O., & Brooks, N.L. (2012). Effects of dietary intake of red palm oil on fatty acid composition and lipid profiles in male Wistar rats. African Journal of Biotechnology, 11(33), 8275-8279.

Benjamin, S.E., & Abbass, A. (2019). Effect of superfatting agents on soaps properties. Journal of Oil Palm Research, 31(2), 304-314.

Betsy, K.J., Jilu, M., Fathima, R., & Varkey, J.T. (2012). Determination of Alkali Content & Total Fatty Matter in Cleansing Agents. Asian Journal of Science and Applied Technology, 2(1), 8-12.

Bondi, C.A.M., Marks, J.L., Wroblewski, L.B., Raatikainen, H.S., Lenox, S.R., & Gebhardt, K.E. (2015). Human and environmental toxicity of sodium lauryl sulfate (SLS): Evidence for safe use in household cleaning products. Environmental Health Insights, 9, 27-32.

Chompoo, M., Damrongwattanakool, N., & Raviyan, P. (2019). Effect of chemical degumming process on physicochemical properties of red palm oil. Songklanakarin Journal of Science and Technology, 41(3), 513-521.

Choo Y.M., Ma, A.N., Ooi, C.K., Yap, S.C., & Basiron, Y. (1993). Red palm oil : A carotene rich nutritious oil. PORIM Information Series No. 11. Palm Oil Research Institute of Malaysia: Kuala Lumpur, Malaysia.

Dauqan, E., Sani, H.A., Abdullah, A., Muhamad, H., & Top, Ab.G.Md. (2011). Vitamin E and beta carotene composition in four different vegetable oils. American Journal of Applied Sciences, 8(5), 407-412.

Edem, D.O., & Akpanabiatu, M.I. (2006). Effects of palm oil-containing diets on enzyme activities of rats. Pakistan Journal of Nutrition, 5(4), 301-305.

Fabien, D.D.F., N.N. Annie, N.N., Adélaide, D.M., Florian, S., & Inocent, G. (2014). Effect of heating and of short exposure to sunlight on carotenoids content of crude palm oil. Journal of Food Processing & Technology, 5(4), 1-6.

Hosni, M.H., & Rus, A.Z.M. (2021). The Physical characteristics of handmade soap with plant-based additives. Research Progress in Mechanical and Manufacturing Engineering, 2(2), 848-859.

Intahphuak, S., Khonsung, P., Panthong, A. (2010). Antiinflammatory, analgesic, and antipyretic activities of virgin coconut oil. Pharmaceutical Biology, 48(2), 151-171.

Ilomuanya, M.O., & Oforkaja, C.A. (2020). Formulation and characterization of palm olein/caprylic triglycerides ester based emulgel for topical use. African Journal of Pharmaceutical Research & Development, 12(2), 172-180.

Imoisi, O., Ilori, G., Agho, I., & Ekhator, J. (2015). Palm oil, its nutritional and health implications (review). Journal of Applied Sciences and Environmental Management, 19(1), 127-133.

Khongcharean, S., Sridokchan, W., Tanya, P., Liengsakul, P., & Ritiron, R. (2014). Rapid assessment of beta-carotene content in oil palm fruit. Khon Kaen Agriculture Journal, 42(1), 375-381. (in Thai)

Kifli, H., & Krishnan, S. (1988). Palm oil products in soap making including measurement of properties of the soap developed, in proceedings of the 1987 international oil palm/palm oil conference-progress and prospects. Conference II: Technology. (pp. 304-315). Palm Oil Research Institute of Malaysia (PORIM). Selangor.

Kuntom, A., & Kifli, H. (1994). Palm-based soap in selected readings on palm oil and its uses. (pp.183-196). Palm Oil Research Institute of Malaysia (PORIM), Malaysia.

Kuntom, A., Kifli, H., & Lim, P.K. (1996). Chemical and physical characteristics of soap made from distilled fatty acids of palm oil and palm kernel oil. Journal of American Oil Chemists’ Society, 73, 105-108.

Lademann, J., Schanzer, S., Meinke, M., Sterry, W., & Darvin, M.E. (2011). Interaction between carotenoids and free radicals in human skin. Skin Pharmacology and Physiology, 24(5), 238-244.

Leow, S., Fairus, S., & Sambanthamurthi, R. (2022). Water-soluble palm fruit extract: Composition, biological properties, and molecular mechanisms for health and non-health applications. Critical Reviews in Food Science and Nutrition, 62(32), 9076-9092.

Mahdi, E.S., Noor, A.M., Sakeena, M.H., Abdullah, G., Abdulkarim, M.F., & Sattar, M.A. (2011). Formulation and in vitro release evaluation of newly synthesized palm kernel oil esters-based nanoemulsion delivery system for 30% ethanolic dried extract derived from local Phyllanthus urinaria for skin antiaging. International Journal of Nanomedicine, 6, 2499-2512.

Mba, O.I., Dumont, M.J., & Ngadi, M. (2015). Palm oil: Processing, characterization, and utilization in the food industry- a review. Food BioScience, 10, 26-41.

Nagendran, B., Unnithan, U.R., Choo, Y.M., & Kalyana, S. (2000). Characteristics of red palm oil, a carotene-and vitamin E-rich refined oil for food uses. Food and Nutrition Bulletin, 21(2), 189-194.

Nainggolan, M., & Sinaga, A.G.S. (2021). The modification of red palm oil and palm kernel oil as antibacterial liquid soap. Rasayan Journal of Chemistry, 14(1), 36-40.

Ogunsuyi, H.O., & Akinnawo, C.A. (2012). Quality assessment of soaps produced from palm bunch ash-derived alkali and coconut oil. Journal of Applied Sciences and Environmental Management, 16(4), 363-366.

Oluwatoyin, S.M. (2011). Quality of soaps using different oil blends. Journal of Microbiology and Biotechnology Research, 1(1),29-34.

Osuala, N., Ezechukwu, L.A., & Tony, P.O. (2021). Screening of wound healing effect of elaeis guineensis oil, extract of vernonia amygdalina mixed with dried egg albumin on burn wound inflicted guinea pig. World Journal of Biology Pharmacy and Health Sciences, 8(1), 13-28.

Owoyele, B.V., & Owolabi, G.O. (2014). Traditional oil palm (Elaeis guineensis jacq.) and its medicinal uses: A review. Tang Humanitas. Medicine, 4(3), e16.

Phanstiel, O., Dueno, E., & Wang, Q.X. (2009). Synthesis of exotic soaps in the chemistry laboratory. Journal of Chemical Education, 75(5), 612-614.

Ramli, S., Norhman, N., Zainuddin, N., Ja’afar, S.M., & Rahman, I.A. (2017). Nanoemulsion based palm olein as vitamin E carrier. Malaysian Journal of Analytical Sciences, 21(6), 1399-1408.

Sar, S.K., Verma, C., & Pandey, P.K. (2008). Spectrophotometric determination of sodium lauryl sulfate as a prime anionic surfactant and contaminant in central east Chhattisgarh (Durg-Bhilai region). Rasayan Journal Chemistry, 1(2), 236-245.

Sinaga, A. G. S., & Siahaan, D. (2019). Antioxidant activity of bioactive constituents from crude palm oil and palm methyl ester. International Journal of Oil Palm, 2(1), 46-52.

Sinaga, A.G.S., Siahaan, D., & Sinaga, K.R. (2018). Potensi minyak sawit merah dan karotenoid sebagai suplemen antioksidan dalam pengujian toleransi glukosa pada tikus putih (Preliminary Study). TALENTA Conference Series. 1, 251-256.

Soni, H., Kaur, M., & Verma, M. (2024). Recent advances in the production of soap from used cooking oil for environment remediation. E3S Web of Conferences, 03014, 1-8.

Tan, C.H., Lee, C.J., Tan, S.N., Poon, D.T.S., Chong, C.Y.E., & Pui, L.P. (2021). Red palm oil; a review on processing, health benefits and its application in food. Journal of Oleo Science, 70(9), 1201-1210.

Tanumihardjo, S.A. (2002). Factor influencing the conversion of carotenoids to retinol: bioavailability to bioconversion to bioefficacy. International Journal for Vitamin and Nutrition Research, 72(1), 40-45.

Tarun, J., Susan, J., Jacob Suria, V.J.S., & Criton, S. (2014). Evaluation of pH of bathing soaps and shampoos for skin and hair care. Indian Journal of Dermatology, 59(2), 442-444.

There, U.G., Kalambe, S., & Choudhary, V. (2022). Formulation of hand made soap by using goat milk. International Journal for Research in Applied Science & Engineering Technology, 10(2), 955-960.

Tripetchkul, S., Pundee, K., & Akeprathymchai. (2013). Utilization of by-products Derived from the Virgin Coconut Oil Manufacturing Process for Soap Preparation. KMUTT Research and Development Journal, 36(4), 439-450. (in Thai)

Viorica, P., Alina, S., & Simona, D. (2011) Quality Control and Evaluation of Certain Properties for Soap Made in Romania. Scientific Study & Research Chemistry & Chemical Engineering, Biotechnology, Food Industry, 12(3), 257-261.

Vidal, N.P., Adigun, O.A., Pham, T.H., Mumtaz, A., Manful, C., Callahan, G., Stewart, P., Keough, D., & Thomas, R.H. (2018). The Effects of cold saponification on the unsaponified fatty acid composition and sensory perception of commercial natural herbal soaps. Molecules, 23(9), 2356-2376.

Widyasanti, A., Ginting, A.M.L., Asyifani, E., & Nurjanah, S. (2018). The production of paper soaps from coconut oil and virgin coconut oil (VCO) with the addition of glycerine as plasticizer. IOP Conference Series: Earth and Environmental Science, 141(1), 1-13.

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Published

2024-11-05

How to Cite

Meepun, N., & Noparat, P. . (2024). Analysis of Beta-Carotene, Tocopherol and Fatty Acid in Red Palm Oil for Development as Soap Products . Burapha Science Journal, 29(3 September-December), 1047–1063. Retrieved from https://li05.tci-thaijo.org/index.php/buuscij/article/view/369